ࡱ>  .nbjbj?? $N]].f  \nVjWmmmmmmmVVVVVVVWzZ:VmmmmqVmm(Vu"mmVmVu@IC+hn&"B&eC>V0nV'B"ZZLICICmmm :    Chemistry 232 Section 01 Spring 2007 Number: CHEM 232-01 Title: General Chemistry II Credits: 3 Schedule: MWF 1:30PM Room: SS-228 Instructor: John Hansen E-mail: hansen@southwestmsu.edu Phone: 537-7349 (office) or 532-5583 (home) Required text: T.E. Brown, H.E. LeMay, and B.E. Bursten, Chemistry: The Central Science, 10thEd. Prentice Hall (2006). ISBN 0131096869 General information This course is the continuation of General Chemistry I. The two-semester sequence of General Chemistry is the first college chemistry course appropriate for chemistry, biology and other science majors including pre-medical and other medical-related pre-professional students. Except in rare circumstances, a student should not take this course without first taking General Chemistry I. Just as with General Chemistry I, this course will take about twice as much of your time as the average college course. You must be willing to work hard to succeed. Expectations Students are expected to attend class, work assigned problems, and to take exams on the dates scheduled. All students should keep a notebook devoted exclusively to problem assignments for this course. This should be a bound or spiral notebook; loose sheets of paper will not be accepted. The notebook will be collected and checked at random, unannounced times. Problem assignments will be announced in class and class attendance will occasionally be checked. Unannounced quizzes and other activities will occasionally be done. Students may be asked to turn in occasional problem assignments on the Web. Performance on assignments, homework problems, and in-class assignments will affect the final grade. In general, students will be expected to show that they are doing the work necessary to keep up with the course material and succeed. All students will have access to the course's Web site on D2L. Check it frequently for announcements. You will be responsible for information contained there. The schedule for examinations is as follows: Exam 1Monday, February 5 during classExam 2Monday, February 26 during classExam 3Monday, March 26 during classExam 4Wednesday, April 18 during classFinal ExamThursday, May 10, 8:00AM-9:50AMThe examinations will be a mixture of multiple choice, short answer, and problem-solving exercises. Each covers approximately 2 chapters of the text, except for the final which covers all of the material for the course. Exams 1-4 are not intended to be comprehensive. However, because the course material all builds on previously-learned material, anything studied up until that date may be considered fair game for an exam. Help with the course As instructor, I intend to be available to you anytime you can find me for assistance. I will post and announce office hours. In addition, you are free to call me at home until 10PM any evening for any questions related to the course. You may also contact me via e-mail with course questions. In order to encourage office hour visits and e-mail inquiries, I will monitor these and give some course credit for students who demonstrate to me that they are trying to master the course material. I also encourage students to help each other with the course material. To assist in this endeavor, I will set up an on-line Discussion Board in the D2L system. Here, students will be encouraged to help each other. To encourage this process, I will monitor Discussion Board activity and may give some extra credit points to students who are active on the Discussion Board and who are especially helpful in answering other students' questions. Grading Grades will be based on a point system. There will be a nominal total of 1000 possible points in addition to small amount of extra-credit points. The breakdown of points and the determination of the grade are discussed below. Examinations The bulk of the course score is determined by the examinations. Each of the 4 regular exams is worth 125 points and the final is worth 300 points. This accounts for 800 points total or 80% of the course score. The scores on the Exams 1-4 may be improved in the following manner. If the percentage score on the final exam is better than the percentage score on any of the earlier exams, the score on the final will be allowed to replace those earlier exam scores (rescaled to 125 points). In other words, for each exam, the score used to determine the grade will either be that actual exam score or the (rescaled) final exam score, whichever is highest. It is even theoretically possible for a student to do much better on the final than any of the earlier exams and have their entire exam score based entirely on the final. With this system, any student, regardless of their performance to date, has the possibility of earning a good grade in the course. With this grading system in place, there will be no make-ups for missed examinations for any reason. Any (or all) of the exams can be made up by the final. Assignment points Another 200 points will be awarded for homework and assignments. Problem notebooks will occasionally be checked for timely completion. This will account for approximately half of the 200 points will be awarded for keeping this notebook up to date. The remainder will be based upon random class attendance checks, and completion of in-class quizzes, group exercises and various class assignments. It is my intention that all students who diligently keep up with the assignments and come to class on regular basis will earn all 200 points. Extra credit A relatively small number of additional points may be awarded for extra credit. These may be from things like attendance at a science seminar, participation in special projects, or completing particularly challenging extra credit problems on exams or extra worksheets. The amount of credit available in this manner will be very limited. Please do not expect or rely upon extra credit to earn your grade. And, please do not approach me toward the end of the semester asking if you can improve a poor grade through extra credit work. Final grade Summarizing the point distribution, Exam 1125Exam 2125Exam 3125Exam 4125Final Exam300Assignment points200Extra credit(small number of additional points)Total1000+The final grades will be at least as high as those in the following table: GradePoints earnedA>930-900-929+870-899830-869-800-829+770-799730-769-700-729+670-699630-669-600-629<600The actual grade may be higher than this. At the end of the semester, I will decide on grade cutoffs based upon my subjective impression of the class's performance. For example, the B/A cutoff may be somewhere between 850 and 900 instead of strictly at 900 and the B/C cutoff may be somewhere between 700 and 800 instead of at 800. However, I will guarantee that your final grade will be at least as high as those in the above table. Academic honesty Cheating on exams and misrepresenting another's work as your own are very serious infractions. The consequences for such behavior range from scoring a 0 on the affected exam or assignment to a failing grade for the course and, ultimately, to suspension from the university for serious repeat infractions. Incidents of academic dishonesty will be result in punitive consequences to the maximum extent allowed by university policy. Please consult the HYPERLINK "http://www.southwestmsu.edu/academic_affairs/academic_information.pdf" \t "_blank"student handbook for the policies and procedures regarding academic honesty. Disclaimer This syllabus is tentative and subject to change at any time. In particular, circumstances may arise requiring rescheduling of examinations. Any such changes will be announced in class or on the course Web site. Students will be held responsible for any information presented in class whether or not they are present. Chemistry 232 Challenge program Spring 2007 Number: CHEM 232 Title: General Chemistry II Credits: 3 E-mail: hansen@southwestmsu.edu Phone: 537-7349 (office) or 532-5583 (home) Required text: T.E. Brown, H.E. LeMay, and B.E. Bursten, Chemistry: The Central Science, 10thEd. Prentice Hall (2006). ISBN 0131096869 General information This course is the continuation of General Chemistry I. The two-semester sequence of General Chemistry is the first college chemistry course appropriate for chemistry, biology and other science majors including pre-medical and other medical-related pre-professional students. Except in rare circumstances, a student should not take this course without first taking General Chemistry I. Just as with General Chemistry I, this course will take about twice as much of your time as the average college course. You must be willing to work hard to succeed. Expectations Courses in the Challenge Program are offered jointly by high schools and by SMSU. I (Prof. Hansen)am the official instructor for the course although the day to day work will be done with the teacher at your school. The exams and assignments will be identical to those given in the on-campus section of the same course and grades will be determined by me. You are expected to participate fully in the class at your school. This includes working assigned problems in a timely manner an participating in all classroom activities that your teacher deems appropriate. Your teacher will evaluate your performance on problem assignments and class activities and report this evaluation to me. There will be four examinations in addition to a final. The examinations will be a mixture of multiple choice, short answer, and problem-solving exercises. Each covers 2 chapters of the text, except for the final which covers all of the material for the course, the first 10 chapters of Brown's text. Exams 1-4 are not intended to be comprehensive. However, because the course material all builds on previously-learned material, anything studied up until that date may be considered fair game for an exam. In addition to your teacher and the resources available at your high school, you are also free to contact me directly with questions about the course material especially via e-mail. Grading Grades will be based on a point system. There will be a nominal total of 1000 possible points in addition to small amount of extra credit points. The breakdown of points and the determination of the grade are discussed below. Examinations The bulk of the course score is determined by the examinations. Each of the 4 regular exams is worth 125 points and the final is worth 300 points. This accounts for 800 points total or 80% of the course score. The scores on the Exams 1-4 may be improved in the following manner. If the percentage score on the final exam is better than the percentage score on any of the earlier exams, the score on the final will be allowed to replace those earlier exam scores (rescaled, of course, to 125 points). In other words, for each exam, the score used to determine the grade will either be that actual exam score or the (rescaled) final exam score, whichever gives the highest score. It is even theoretically possible for a student to do much better on the final than any of the earlier exams and have their entire exam score based entirely on the final. With this system, any student, regardless of their performance to date, has the possibility of earning a good grade in the course. With this grading system in place, there will be no make-ups for missed examinations for any reason. Any (or all) of the exams can be made up by the final. Assignment points Another 200 points will be awarded for homework and assignments. Problem notebooks will occasionally be checked for timely completion. This will account for approximately half of the 200 points. The rest will be awarded on the basis of class participation and performance in regular in-class activities. Your teacher will be responsible for evaluating this portion of the grade. It is my intention that all students who diligently keep up with the assignments and actively participate in class will earn all 200 points. Extra credit A relatively small number of additional points may be awarded by me or your teacher for extra credit. These may be from things like attendance at a science seminar, participation in special projects, or completing particularly challenging extra credit problems on exams or extra worksheets. The amount of credit available in this manner will be very limited. Do not expect or rely upon extra credit to earn your grade. Final grade Summarizing the point distribution, Exam 1125Exam 2125Exam 3125Exam 4125Final Exam300Assignment points200Extra credit(small number of additional points)Total1000+The final grades will be at least as high as those in the following table: GradePoints earnedA>930-900-929+870-899830-869-800-829+770-799730-769-700-729+670-699630-669-600-629<600The actual grade may be higher than this. At the end of the semester, I will decide on grade cutoffs based upon my subjective impression of the students' performance in the on-campus and the Challenge sections of the course. For example, the B/A cutoff may be somewhere between 850 and 900 instead of strictly at 900 and the B/C cutoff may be somewhere between 700 and 800 instead of at 800. I will use the same cutoffs in all sections of the course and I will guarantee that your final grade will be at least as high as those in the above table. Schedule and assignments The schedule below shows all of the problem assignments for the class. It also shows the dates that the chapters will be covered at SMSU along with the dates of the on-campus examinations. Your teacher will give you the corresponding schedule at your school. The problem assignments are taken from the 10th Edition of the text by Brown. If you are using an earlier edition, your teacher will either provide you with an appropriate problem set from the old text or will give you a copy of the problems from the 10th Edition. Dates (to be supplied by your teacher)Dates at SMSUChapters from Brown, etal.Problem assignments (from 10th Ed.)Exams1/18-1/2611: Intermolecular forces9, 10, 13, 15, 18, 20, 23, 26, 34, 36, 38, 41, 43, 44, 48, 50, 51, 54, 55, 56, 57, 59, 61, 64, 66, 69, 71, 74, 75, 78, 79, 81, 831/29-2/213: Solution properties12, 21, 22, 26, 28, 29, 32, 33, 36,38, 41, 44, 46, 49, 50, 54, 55, 56, 59, 63, 65, 69, 72, 74, 76, 77, 83, 85, 87, 94, 1002/5Exam 12/9-2/1414: Chemical kinetics12, 13, 15, 19, 20, 22, 25, 27, 31, 33, 36, 39, 43, 44, 49, 53, 54, 56, 69, 70, 71, 78, 792/19-2/2315: Equilibrium9, 10, 13, 15, 17, 20, 21, 25, 28, 30, 34, 36, 39, 42, 44, 46, 47, 50, 52, 59, 60, 69, 713/2Exam 22/26-2/28 and 3/12-3/16 (before and after break)16: Acid-base equilibria15, 16, 18, 19, 21, 23, 24, 26, 29, 31, 34, 37, 38, 40, 41, 44, 46, 47, 52, 55, 57, 59, 63, 64, 66, 73, 75, 78, 81, 82, 84, 86, 88, 90, 93, 95, 101, 103, 109, 1123/19-3/2317: Other aqueous equilibria11, 13, 20, 21, 26, 27, 31, 35, 37, 39, 40, 43, 47, 49, 52, 53, 55, 61, 63, 65, 68, 69, 71, 77, 78, 81, 88, 903/26Exam 34/2-4/619: Chemical thermodynamics7, 12, 16, 20, 21, 23, 28, 29, 32, 34, 38, 39, 42, 47, 50, 53, 56, 63, 64, 66, 71, 74, 77, 79, 82, 84, 87, 90, 914/9-4/1620: Electrochemistry13, 14, 15, 17, 19, 20, 23, 28, 31, 34, 35, 37, 39, 40, 43, 44, 45, 47, 49, 51, 59, 61, 63, 69, 71, 74, 77, 79, 81, 86, 89, 91, 94, 1064/18Exam 44/23-4/2521: Nuclear chemistry7, 9, 14, 15, 18, 24, 26, 27, 28, 48, 49, 784/27-4/3022: Selected chemistry of nonmetals19, 20, 22, 25, 42, 44, 45, 48, 49, 55, 56, 59, 62, 67, 685/2-5/318: Atmospheric chemistry9, 10, 12, 15, 17, 19, 24, 25, 27, 29, 305/10Final Exam Chemistry 232L Sections 31 and 32 Spring 2007 Number: CHEM 231L Title: General Chemistry II Lab Credits: 2 Schedule Common meeting time for both sections: T 1:00-1:50PM Section 31: W 6:30-9:20PM Section 32: T 2:00-4:50PM Room: ST-260 Instructors: John Hansen Required text: Postma, Roberts, and Hollenberg, Chemistry in the Laboratory, (selections published as a custom textbook for this course) W.H. Freeman (2006). ISBN 1-4292-0549-0. Note: This is a different text than the lab manual used in Gen Chem I. General information This is the laboratory course to accompany Chemistry 232 General Chemistry II. Although it is closely coordinated with the lecture course, at SMSU it is treated as a completely separate course carrying its own credit and grade. Class schedule This course begins during the week of January 22, the week after classes begin for Spring Semester 2007. Sections 31 and 32 meet together every Tuesday at 1:00 PM for pre-lab discussions and lab quizzes. The sections separate for doing lab work, with section 32 continuing immediately after the common meeting time on Tuesday and section 31 meeting on Wednesday evening at 6:30. There is no lab during the semester break or during the week of the Spring National ACS meeting which the instructor will be attending. The first 4 weeks consist of a "mini-course" on qualitative analysis. A scheme for qualitative analysis of certain ions is introduced and applied to water samples. This material is covered in Labs 6 and 7 from the lab manual. (If this material is completed before the end of the 4 weeks, Lab 10 will be done as an additional experiment.) When the qualitative analysis course is completed, Labs 1-5 and 8 will be done in numerical order, one experiment for each week of lab. Following these experiments, Lab 12 will be done as a 2-week project. The last week will be devoted to check-out, lab cleanup, makeups, and the last lab quiz. Expectations Students are expected to be present for all laboratory sessions. Students may be excused from attendance only for very serious illness or personal emergency which must be documented and approved in advance of the missed class. Such absences do not excuse the student from completing all assigned lab work; special arrangements such as attendance at other lab sections must be made in order to make up any missed work. Because of the difficulty of scheduling make-up work, it will be impossible to accommodate more than two absences regardless of excuse. Students experiencing a long-term illness or other similar event requiring an extended absence may have no choice other than withdrawal from the course or a grade of incomplete (I). A grade of I will only be given on recommendation from the Dean. Each student must have an approved bound laboratory notebook and must bring this notebook to every class. The notebook must contain a summary of each experiment, observations, and analysis. All observations must be entered directly into the notebook. A copy of the notebook entries for each experiment are to be turned in as a lab report at the completion of each experiment at the beginning of the next lab session. The requirements for the notebook and the expectations for reports will be discussed during the first lab session. Each week a new experiment is begun, students are expected to be have prepared by reading the lab procedure and making appropriate entries into the notebook. Quizzes There will be four lab quizzes. Each quiz may cover any of the experiments done to that point. Students will be allowed to use their laboratory notebooks - and no other sources - for these quizzes. Formal reports Three formal written reports are required. A format for these reports, along with other expectations, will be given in class. The first report will cover the qualitative analysis part of the course. The second will be over one of the one-week experiments. Students may have a choice of labs to use for this report; this will be announced in class. The third report will cover Lab 12. Grading Grades will be based on a point system. There will be a total of 200 possible points. The weekly reports from the notebook, along with a final evaluation of the notebook, will count for 60 points total. There are 9 regular labs. Each of the 4 quizzes is worth 20 points and each formal report is worth 20 points. Notebook60Quizzes; 4 @ 20 each80Formal reports; 3 @ 20 each60Total200The final grades will be at least as high as those in the following table. The actual grade may be higher. GradePoints earnedA>186-180-185+174-179166-173-160-165+154-159146-153-140-145+134-139126-133-120-125<120Calendar The following calendar shows the schedule of labs, the dates of quizzes, and the due dates for formal reports. Dates (T and W)LabsQuizzesFormal reports1/23-24Labs 6 and 7 (cont.) Qualitative analysis1/30-31Labs 6 and 7 (cont.) Qualitative analysis2/6-7Labs 6 and 7 (cont.) Qualitative analysis2/13-14Labs 6 and 7 (cont.) or Lab 10 Qualitative analysis or Some nonmetal chemistryQuiz 12/20-21Lab 1 Colligative properties2/27-28Lab 2 Equilibrium examplesReport 1 due3/6-7Lab 3 Molar mass and K of an acidQuiz 23/13-14Mid-semester break; no lab3/20-21Lab 4 Analysis of hard water3/27-28ACS meeting; no lab4/3-4Lab 5 Solubility product of calcium iodate4/10-11Lab 8 Electrochemical cellsQuiz 3Report 2 due4/17-18Lab 12; part 1 Analysis of iron in blood4/24-25Lab 12; part 2 Analysis of iron in blood5/1-2Check-out; final quiz; make-upsQuiz 4Report 3 due by end of weekDisclaimer This syllabus is tentative and subject to change at any time. Any such changes will be announced in class or on the course Web site. Students will be held responsible for any information presented in class whether or not they are present. Chemistry 232L SMSU Challenge Program Spring 2007 Number: CHEM 231L Title: General Chemistry II Lab Credits: 2 Required text: Postma, Roberts, and Hollenberg, Chemistry in the Laboratory, (selections published as a custom textbook for this course) W.H. Freeman (2006). ISBN 1-4292-0549-0. Note: This is a different text than the lab manual used in Gen Chem I. General information This is the laboratory course to accompany Chemistry 232 General Chemistry II. Although it is closely coordinated with the lecture course, at SMSU it is treated as a completely separate course carrying its own credit and grade. Class schedule The several lab periods will be devoted to a "mini-course" on qualitative analysis. A scheme for qualitative analysis of certain ions is introduced and applied to water samples. This material is covered in Labs 6 and 7 from the lab manual. (If this material is completed before expected, Lab 10 may be done as an additional experiment.) When the qualitative analysis course is completed, Labs 1-5 and 8 will be done in numerical order. Following these experiments, Lab 12 will be done as a multi-period project. Expectations Each student must have an approved bound laboratory notebook and must bring this notebook to every class. The notebook must contain a summary of each experiment, observations, and analysis. All observations must be entered directly into the notebook. A copy of the notebook entries for each experiment are to be turned in as a lab report at the completion of each experiment at the beginning of the next lab session. The requirements for the notebook and the expectations for reports will be discussed during the first lab session. Each week a new experiment is begun, students are expected to be have prepared by reading the lab procedure and making appropriate entries into the notebook. Quizzes There will be four lab quizzes. Each quiz may cover any of the experiments done to that point. Students will be allowed to use their laboratory notebooks - and no other sources - for these quizzes. Formal reports Three formal written reports are required. A format for these reports, along with other expectations, will be given in class. The first report will cover the qualitative analysis part of the course. The third report will cover Lab 12. Students may have a choice of several laboratories to use for the intervening formal report. This will be announced in class. Grading Grades will be based on a point system. There will be a total of 200 possible points. The weekly reports from the notebook, along with a final evaluation of the notebook, will count for 60 points total. There are 9 regular labs. Each of the 4 quizzes is worth 20 points and each formal report is worth 20 points. Notebook60Quizzes; 4 @ 20 each80Formal reports; 3 @ 20 each60Total200The final grades will be at least as high as those in the following table. The actual grade may be higher. GradePoints earnedA>186-180-185+174-179166-173-160-165+154-159146-153-140-145+134-139126-133-120-125<120Schedule of Experiments Experiments will be completed on a schedule determined by your teacher. The following table show the experiments in the order that they will be done in the on-campus course at SMSU. It also shows the dates that the experiments will be done at SMSU and the dates of lab quizzes. Changes to the experiments or to their order may be made depending upon the local situation at your school. Dates (to be supplied by your teacher)Dates at SMSUExperimentReference from customized lab manual1/23, 1/30, 2/6, 2/13Qualitative analysisLabs 6, 7(Possible addition)2/13Some nonmetal chemistryLab 102/13Lab quiz 12/20Colligative propertiesLab 12/27Equilibrium examplesLab 23/13Molar mass and K of an acidLab 33/13Lab quiz 23/20Analysis of hard waterLab 44/3Solubility product of calcium iodateLab 54/3Lab quiz 34/10Electrochemical cellsLab 84/17, 4,24Analysis of iron in bloodLab 125/1Lab quiz 4 ( P  <K !*%+%%%%%%(;())5P5 9[9%:*:+:0:::::????????????GG1$$If;Fth ^N tF6    34a$Iffkd0$$If;Fth ^N tF6    34aXXXXXXY Yfkd1$$If;Fth ^N tF6    34a$If Y Y YYYY-fkd2$$If;Fth ^N tF6    34a$IffkdV2$$If;Fth ^N tF6    34aYYY%Y&Y(Y*Y/Yfkdn3$$If;Fth ^N tF6    34a$If/Y0Y9YYYYYY $$Ifa$gd,Igd,Ifkd3$$If;Fth ^N tF6    34aYYYZ Z ZUOOOO$Ifkd4$$If;\b$! t0634abYYZZ>ZJZsZZZZZZZZZZ [&[)[5[=[^[_[e[q[[[[[[[ \\5\6\<\=\I\S\{\\\\\\\\\^^_!_"_i_gaa i%i&i)iiiiikllll'l(lLlflzlllllllllmh,I0J56\]h,I0J5\ h,I6]h,I56\] h,I5\h,IR Z ZZ?ZAZCZUOOOO$IfkdQ5$$Ifg\b$! t0634abCZDZJZtZvZxZUOOOO$Ifkd6$$Ifg\b$! t0634abxZyZZZZZUOOOO$Ifkd6$$Ifg\b$! t0634abZZZZ[[UOOOO$Ifkd7$$Ifg\b$! t0634ab[[ ['[)[6[UOOOO$Ifkd}8$$Ifg\b$! t0634ab6[7[=[_[f[h[UOOOO$IfkdH9$$Ifg\b$! t0634abh[i[q[[[[UOOOO$Ifkd:$$Ifg\b$! t0634ab[[[[[[UOOOO$Ifkd:$$Ifg\b$! t0634ab[[[[[[UOOOO$Ifkd;$$Ifg\b$! t0634ab[[[ \\\UOOOO$Ifkdt<$$Ifg\b$! t0634ab\\\6\=\J\UOOOO$Ifkd?=$$Ifg\b$! t0634abJ\K\S\|\~\\UOOOO$Ifkd >$$Ifg\b$! t0634ab\\\\\\UOOOO$Ifkd>$$Ifg\b$! t0634ab\\\\\]UOOOO$Ifkd?$$Ifg\b$! t0634ab]] ]]]/^B^UPKF>6 & Fgd,I$a$gd,Igd,Igd,Igd,Ikdk@$$Ifg\b$! t0634abB^c^o^j_l__e`t`zbbd>eFeffgghhhh$Ifgd,Igd,Igd,I & Fgd,Ihhhhhh-fkdA$$If;F ^z  t6    34a$Iffkd6A$$If;F ^z  t6    34ahhiii i&i*ifkdNB$$If;F ^z  t6    34a$If*i+iiiii$Ifgd,IfkdB$$If;F ^z  t6    34aiiiiii-fkdC$$If;Fth ^N tF6    34a$IffkdfC$$If;Fth ^N tF6    34aiiiiiiiifkd~D$$If;Fth ^N tF6    34a$Ifiiiiii-fkdE$$If;Fth ^N tF6    34a$Iffkd E$$If;Fth ^N tF6    34aiiiiiiiifkd"F$$If;Fth ^N tF6    34a$Ifiiij j j-fkd:G$$If;Fth ^N tF6    34a$IffkdF$$If;Fth ^N tF6    34a j jjjjjj%jfkdG$$If;Fth ^N tF6    34a$If%j&j(j*j2j3j-fkdH$$If;Fth ^N tF6    34a$IffkdRH$$If;Fth ^N tF6    34a3j5j8j@jAjCjEjJjfkdjI$$If;Fth ^N tF6    34a$IfJjKjcjkll(lMl$Ifgd,Igd,IfkdI$$If;Fth ^N tF6    34aMlNlPlfl{llUOOOO$IfkdJ$$If:\xz+%D  t0+634abllllllUOOOO$IfkdeK$$If\xz+%D  t0+634abllllllUOOOO$IfkdHL$$If\xz+%D  t0+634abllllllUOOOO$Ifkd+M$$IfX\xz+%D  t0+634ablllmmmUOOOO$IfkdN$$IfX\xz+%D  t0+634abmm#m>mHmLmMmWmbmxmmmmmmmmmmnnnn)n.nh,I h,I5\mmm#m?mEmUOOOO$IfkdN$$If+\xz+%D  t0+634abEmFmHmMmXmZmUOOOO$IfkdO$$Ifv\xz+%D  t0+634abZm[m]mbmymmUOOOO$IfkdP$$Ifv\xz+%D  t0+634abmmmmmmUOOOO$IfkdQ$$If+\xz+%D  t0+634abmmmmmmUOOOO$Ifkd}R$$If+\xz+%D  t0+634abmmmmmmUOOOO$Ifkd`S$$If+\xz+%D  t0+634abmmmmnnUOOOO$IfkdCT$$If+\xz+%D  t0+634abnnnn*n,nUOOOO$Ifkd&U$$If+\xz+%D  t0+634ab,n-n.nUSkd V$$If \xz+%D  t0+634ab":p,I/ =!"#$%$$If!vh5i55 #vi#v#v :V Y tZ 6,5^5 5 34$$If!vh5i55 #vi#v#v :V ; 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